Ustanovení o řízení teploty
2.2.52.1.15 Určité organické peroxidy smějí být přepravovány pouze za podmínek řízené teploty. Řízenou teplotou se rozumí nejvyšší teplota, při které mohou být organické peroxidy bezpečně přepravovány. Předpokládá se, že teplota bezprostředního okolí kusu přesáhne během přepravy hodnotu 55 °C pouze na relativně krátkou dobu za 24-hodinový časový interval. V případě výpadku systému řízení teploty, může být nutné provést nouzová opatření. Kritická teplota je teplota, při níž musí být provedena nouzová opatření.
2.2.52.1.16 Řízená a kritická teplota jsou odvozeny od teploty samourychlujícího se rozkladu SADT (viz tabulku 1), která je definovaná jako nejnižší teplota, při níž může dojít k samourychlujícímu se rozkladu pro látku v obalu použitém během přepravy. SADT musí být stanovena za účelem rozhodnutí, zda látka musí být přepravována při řízené teplotě. Předpisy pro stanovení SADT jsou obsaženy v Příručce zkoušek a kritérií, části II, oddílu 20 a pododdílu 28.4.
Tabulka 1: Odvození řízených a kritických teplot
+-------------+----------------+-------------------+------------------+
| Druh | SADT a) | Řízená teplota | Kritická teplota |
| nádoby | | | |
+-------------+----------------+-------------------+------------------+
| Samostatné | 20 °C a méně | o 20 °C nižší než | o 10 °C nižší |
| obaly a IBC | | SADT | než SADT |
| +----------------+-------------------+------------------+
| | 20 °C až 35 °C | o 15 °C nižší než | o 10 °C nižší |
| | | SADT | než SADT |
| +----------------+-------------------+------------------+
| | více než 35 °C | o 10 °C nižší než | o 5 °C nižší |
| | | SADT | než SADT |
+-------------+----------------+-------------------+------------------+
| Cisterny | nejvýše 50 °C | o 10 °C nižší než | o 5 °C nižší |
| | | SADT | než SADT |
+-------------+----------------+-------------------+------------------+
a) SADT látky zabalené pro přepravu
2.2.52.1.17 Tyto organické peroxidy musí být přepravovány při řízené teplotě:
- organické peroxidy typu B a C se SADT ≤ 50 °C;
- organické peroxidy typu D se SADT ≤ 50 °C, vykazující střední účinek při zahřívání v uzavřeném prostoru, nebo se SADT ≤ 45 °C, vykazující při zahřívání v uzavřeném prostoru malý nebo žádný účinek; a
- organické peroxidy typů E a F se SADT ≤ 45 °C.
Poznámka: Předpisy pro stanovení účinků při zahřívání v uzavřeném prostoru jsou uvedeny v Příručce zkoušek a kritérií, část II, oddílu 20 a pododdílu 28.4.
2.2.52.1.18 Řízené a kritické teploty jsou uvedeny v pododdílu 2.2.52.4. Skutečná teplota během přepravy smí být nižší než řízená teplota, avšak musí být stanovena tak, aby nedošlo k nebezpečnému oddělování (separaci) fází.
2.2.52.2 Látky nepřipuštěné k přepravě
Organické peroxidy typu A není podle ustanovení třídy 5.2 dovoleno přepravovat [viz Příručku zkoušek a kritérií, část II, odstavec 20.4.3 (a)];
2.2.52.3 Seznam hromadných položek
+------------------------------------------------------------------------------------------+
| Klasifikační UN Pojmenování látek nebo předmětů |
| kód číslo |
+------------------------------------------------------------------------------------------+
Organické peroxidy +-----------------------------------------------------+
| | PEROXID ORGANICKÝ TYP A, KAPALNÝ (není |
| | připuštěn k přepravě, viz 2.2.52.2) |
| | PEROXID ORGANICKÝ TYP A, TUHÝ (není |
| | připuštěn k přepravě, viz 2.2.52.2) |
| | 3101 PEROXID ORGANICKÝ TYP B, KAPALNÝ |
| | 3102 PEROXID ORGANICKÝ TYP B, TUHÝ |
| | 3103 PEROXID ORGANICKÝ TYP C, KAPALNÝ |
+------------------------------------+ 3104 PEROXID ORGANICKÝ TYP C, TUHÝ |
| nevyžadující řízení P1 | 3105 PEROXID ORGANICKÝ TYP D, KAPALNÝ |
| teploty | 3106 PEROXID ORGANICKÝ TYP D, TUHÝ |
| | 3107 PEROXID ORGANICKÝ TYP E, KAPALNÝ |
| | 3108 PEROXID ORGANICKÝ TYP E, TUHÝ |
| | 3109 PEROXID ORGANICKÝ TYP F, KAPALNÝ |
| | 3110 PEROXID ORGANICKÝ TYP F, TUHÝ |
| | PEROXID ORGANICKÝ TYP G, KAPALNÝ |
| | (nepodléhá předpisům třídy 5.2, viz |
| | 2.2.52.1.6) |
| | PEROXID ORGANICKÝ TYP G, TUHÝ |
| | (nepodléhá předpisům třídy 5.2, viz |
| | 2.2.52.1.6) |
| +-----------------------------------------------------+
| +-----------------------------------------------------+
| | 3111 PEROXID ORGANICKÝ TYP B, KAPALNÝ, |
| | S ŘÍZENÍM TEPLOTY |
| | 3112 PEROXID ORGANICKÝ TYP B, TUHÝ, |
| | S ŘÍZENÍM TEPLOTY |
| | 3113 PEROXID ORGANICKÝ TYP C, KAPALNÝ, |
| | S ŘÍZENÍM TEPLOTY |
| | 3114 PEROXID ORGANICKÝ TYP C, TUHÝ, |
| | S ŘÍZENÍM TEPLOTY |
| | 3115 PEROXID ORGANICKÝ TYP D, KAPALNÝ, |
| | S ŘÍZENÍM TEPLOTY |
| vyžadující řízení | 3116 PEROXID ORGANICKÝ TYP D, TUHÝ, |
| teploty P2 | S ŘÍZENÍM TEPLOTY |
+------------------------------------+ |
| 3117 PEROXID ORGANICKÝ TYP E, KAPALNÝ, |
| S ŘÍZENÍM TEPLOTY |
| 3118 PEROXID ORGANICKÝ TYP E, TUHÝ, |
| S ŘÍZENÍM TEPLOTY |
| 3119 PEROXID ORGANICKÝ TYP F, KAPALNÝ, |
| S ŘÍZENÍM TEPLOTY |
| 3120 PEROXID ORGANICKÝ TYP F, TUHÝ, |
| S ŘÍZENÍM TEPLOTY |
+-----------------------------------------------------+
2.2.52.4 Seznam již zařazených organických peroxidů v obalech
Kódy "OP1" až "OP8" uvedené ve sloupci "Způsob balení" se vztahují ke způsobům balení v pododdílu 4.1.4.1, pokynu pro balení P520 (viz též 4.1.7.1). Organické peroxidy, které se mají přepravovat, musí odpovídat klasifikaci a řízeným a kritickým teplotám (odvozeným od SADT), jak jsou uvedeny. K látkám připuštěným v IBC viz 4.1.4.2, pokyn pro balení IBC520 a k látkám připuštěným v cisternách podle kapitol 4.2 a 4.3 viz 4.2.5.2, pokyn pro přemístitelné cisterny T23.
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ORGANICKÝ PEROXID | Koncentrace | Ředidlo | Ředidlo | Inertní | Voda | Způsob | Řízená | Kritická | UN- | Vedlejší |
| | (%) | TYP A | TYP B | tuhá | (%) | balení | teplota | teplota | číslo | nebezpečí |
| | | (%) | (%) 1) | látka | | | (°C) | (°C) | druhové | a poznámky |
| | | | | (%) | | | | | položky | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ACETYLALCETONPEROXID | ≤ 42 | ≥ 48 | | | ≥ 8 | OP7 | | | 3105 | 2) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | | | | OP7 | | | 3106 | 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ACETYLCYKLOHEXANSULFONYL- | ≤ 82 | | | | ≥ 12 | OP4 | -10 | 0 | 3112 | 3) |
| PEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | ≥ 68 | | | OP7 | -10 | 0 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLHYDROPEROXID | ≤ 88 | ≥ 6 | | | ≥ 6 | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXYACETÁT | ≤ 62 | ≥ 38 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXYBENZOÁT | ≤ 100 | | | | | OP5 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXY-2-ETHYLHEXANOÁT | ≤ 100 | | | | | OP7 | +20 | +25 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXY-2- | ≤ 100 | | | | | OP7 | | | 3105 | |
| ETHYLHEXYLKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXYISOPROPYL- | ≤ 77 | ≥ 23 | | | | OP5 | | | 3103 | |
| KARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-PEROXYNEODEKANOÁT | ≤ 77 | | ≥ 23 | | | OP7 | 0 | +10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 47 | ≥ | | | | OP8 | 0 | +10 | 3119 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXY PIVALÁT | ≤ 77 | | ≥ 23 | | | OP5 | +10 | +15 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-AMYLPEROXY-3,5,5- | ≤ 100 | | | | | OP7 | | | 3105 | 3) |
| TRIMETHYLHEXANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLKUMYLPEROXID | > 42 - 100 | | | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP8 | | | 3108 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| n-BUTYL-4,4-DI-(terc- | > 52 - 100 | | | | | OP5 | | | 3103 | |
| BUTYLPEROXY)-VALERÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP8 | | | 3108 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLHYDROPEROXID | > 79 - 90 | | | | ≥ 10 | OP5 | | | 3103 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 80 | ≥ 20 | | | | OP7 | | | 3105 | 4), 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 79 | | | | > 14 | OP8 | | | 3107 | 13), 23) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | | | | ≥ 28 | OP8 | | | 3109 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLHYDROPEROXID + | < 82 + > 9 | | | | ≥ 7 | OP5 | | | 3103 | 13) |
| DI-terc-BUTYLPEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLMONOPEROXYMALEÁT | > 52 - 100 | | | | | OP5 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | ≥ 48 | | | | OP6 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP8 | | | 3108 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | | | OP8 | | | 3108 | |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYACETÁT | > 52 - 77 | ≥ 23 | | | | OP5 | | | 3101 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 32 - 52 | ≥ 48 | | | | OP6 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | ≥ 68 | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYBENZOÁT | > 77 - 100 | | | | | OP5 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 52 - 77 | ≥ 23 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYBUTYLFUMARÁT | ≤ 52 | ≥ 48 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYKROTONÁT | ≤ 77 | ≥ 23 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYETHYLACETÁT | ≤ 100 | | | | | OP5 | +20 | +25 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXY-2- | > 52 - 100 | | | | | OP6 | +20 | +25 | 3113 | |
| ETHYLHEXANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 32 - 52 | | ≥ 48 | | | OP8 | +30 | +35 | 3117 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP8 | +20 | +25 | 3118 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | ≥ 68 | | | OP8 | +40 | +45 | 3119 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXY-2- | ≤ 12 + | ≥ 14 | | ≥ 60 | | OP7 | | | 3106 | |
| ETHYLHEXANOÁT + 2,2-DI-(terc- | ≤ 14 | | | | | | | | | |
| BUTYLPEROXY)-BUTAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 31 + | | ≥ 33 | | | OP7 | +35 | +40 | 3115 | |
| | ≤ 36 | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXY-2- | ≤ 100 | | | | | OP7 | | | 3105 | |
| ETHYLHEXYLKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYISOBUTYRÁT | > 52 - 77 | | ≥ 23 | | | OP5 | +15 | +20 | 3111 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | ≥ 48 | | | OP7 | +15 | +20 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYISOPROPYL | ≤ 77 | ≥ 23 | | | | OP5 | | | 3103 | |
| KARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1-(2-terc- | ≤ 77 | ≥ 23 | | | | OP7 | | | 3105 | |
| BUTYLPEROXYISOPROPYL)-3- | | | | | | | | | | |
| ISOPROPENYLBENZEN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | | | ≥ 58 | | OP8 | | | 3108 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 3-terc-BUTYLPEROXY-2-METHYL | ≤ 100 | | | | | OP5 | | | 3103 | |
| BENZOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYNEODEKANOÁT | > 77 - 100 | | | | | OP7 | -5 | +5 | 3115 | |
| | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | ≥ 23 | | | | OP7 | 0 | +10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | 0 | +10 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | 0 | +10 | 3118 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
| | (zmražené) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | ≥ 68 | | | | OP8 | 0 | +10 | 3119 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYNEOHEPTANOÁT | ≤ 77 | ≥ 23 | | | | OP7 | 0 | +10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | 0 | +10 | 3117 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYPIVALÁT | > 67 - 77 | ≥ 23 | | | | OP5 | 0 | +10 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 27 - 67 | | ≥ 33 | | | OP7 | 0 | +10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 27 | | ≥ 73 | | | OP8 | +30 | +35 | 3119 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXYSTEARYL- | ≤ 100 | | | | | OP7 | | | 3106 | |
| KARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-BUTYLPEROXY-3,5,5- | > 32 - 100 | | | | | OP7 | | | 3105 | |
| TRIMETHYLHEXANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | | | ≥ 58 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | ≥ 68 | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 3-CHLORPEROXYBENZOOVÁ KYSELINA | > 57 - 86 | | | ≥ 14 | | OP1 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 57 | | | ≥ 3 | ≥ 40 | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | | ≥ 6 | ≥ 17 | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KUMYLHYDROPEROXID | > 90 - 98 | ≤ 10 | | | | OP8 | | | 3107 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 90 | ≥ 10 | | | | OP8 | | | 3109 | 13), 18) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KUMYLPEROXYNEODEKANOÁT | ≤ 87 | ≥ 13 | | | | OP7 | -10 | 0 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | ≥ 23 | | | OP7 | -10 | 0 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | -10 | 0 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KUMYLPEROXYNEOHEPTANOÁT | ≤ 77 | ≥ 23 | | | | OP7 | -10 | 0 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KUMYLPEROXYPIVALÁT | ≤ 77 | | ≥ 23 | | | OP7 | -5 | +5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| CYKLOHEXANONPEROXID(Y) | ≤ 91 | | | | ≥ 9 | OP6 | | | 3104 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | ≥ 28 | | | | OP7 | | | 3105 | 5) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | | | | | OP7 | | | 3106 | 5), 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | | ≥ 68 | | | | | Vyhrazeno | 29) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIACETONALKOHOLPEROXID | ≤ 57 | | ≥ 26 | | ≥ 8 | OP7 | +40 | +45 | 3115 | 6) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIACETYLPEROXID | ≤ 27 | | ≥ 73 | | | OP7 | +20 | +25 | 3115 | 7), 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-terc-AMYLPEROXID | ≤ 100 | | | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,2-DI-(terc-AMYLPEROXY)-BUTAN | ≤ 57 | ≥ 43 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1-DI-(terc-AMYLPEROXY)- | ≤ 82 | ≥ 18 | | | | OP6 | | | 3103 | |
| CYKLOHEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIBENZOYLPEROXID | > 51 - 100 | | | ≤ 48 | | OP2 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 77 - 94 | | | | ≥ 6 | OP4 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | | | ≥ 23 | OP6 | | | 3104 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 62 | | | ≥ 28 | ≥ 10 | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 52 - 62 | | | | | OP7 | | | 3106 | 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 35 - 52 | | | ≥ 48 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 36 - 42 | ≥ 18 | | | ≤ 40 | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 56,5 | | | | ≥ 15 | OP8 | | | 3108 | |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | | | OP8 | | | 3108 | 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | | | 3109 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 35 | | | ≥ 65 | | | | | Vyhrazeno | 29) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(4-terc-BUTYLCYKLOHEXYL) | ≤ 100 | | | | | OP6 | +30 | +35 | 3114 | |
| PEROXYDIKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | +30 | +35 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-terc-BUTYLPEROXID | > 52 - 100 | | | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | ≥ 48 | | | OP8 | | | 3109 | 25) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-terc-BUTYLPEROXYAZELÁT | ≤ 52 | ≥ 48 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,2-DI-(terc-BUTYLPEROXY)-BUTAN | ≤ 52 | ≥ 48 | | | | OP6 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1-DI-(terc-BUTYLPEROXY)- | > 80 - 100 | | | | | OP5 | | | 3101 | 3) |
| CYKLOHEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | | ≥ 28 | | | OP5 | | | 3103 | 30) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 52 - 80 | ≥ 20 | | | | OP5 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 42 - 52 | ≥ 48 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | ≥ 13 | | ≥ 45 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | ≥ 58 | | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 27 | ≥ 25 | | | | OP8 | | | 3107 | 21) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 13 | ≥ 13 | ≥ 74 | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1-DI-(terc-BUTYLPEROXY)- | ≤ 43 + | ≥ 41 | | | | OP7 | | | 3105 | |
| CYKLOHEXAN+terc-BUTYLPEROXY-2- | ≤ 16 | | | | | | | | | |
| ETHYLHEXANOAT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-n-BUTYLPEROXYKARBONÁT | > 27 - 52 | | ≥ 48 | | | OP7 | -15 | -5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 27 | | ≥ 73 | | | OP8 | -10 | 0 | 3117 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | -15 | -5 | 3118 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
| | (zmražené) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-sec-BUTYLPEROXYKARBONÁT | > 52 - 100 | | | | | OP4 | -20 | -10 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | ≥ 48 | | | OP7 | -15 | -5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,6-Di-(terc-BUTYLPEROXY- | ≤ 72 | ≥ 28 | | | | OP5 | | | 3103 | |
| KARBONYLOXY)HEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-terc-BUTYLPEROXY | > 42 - 100 | | | ≤ 57 | | OP7 | | | 3106 | |
| ISOPROPYL)-BENZEN(Y) | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | | | ≥ 58 | | | | | Vyhrazeno | 29) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(terc-BUTYLPEROXY)-FTALÁT | > 42 - 52 | ≥ 48 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | | | OP7 | | | 3106 | 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | ≥ 58 | | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,2-DI-(terc-BUTYLPEROXY)- | ≤ 52 | ≥ 48 | | | | OP7 | | | 3105 | |
| PROPAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 | ≥ 13 | | ≥ 45 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1-DI-(terc-BUTYLPEROXY)- | > 90 - 100 | | | | | OP5 | | | 3101 | 3) |
| 3,3,5-TRIMETHYLCYKLOHEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 90 | | ≥ 10 | | | OP5 | | | 3103 | 30) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 57 - 90 | ≥ 10 | | | | OP5 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | ≥ 23 | | | OP5 | | | 3103 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 57 | | | ≥ 43 | | OP8 | | | 3110 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 57 | ≥ 43 | | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | ≥ 26 | ≥ 42 | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DICETYLPEROXYDIKARBONÁT | ≤ 100 | | | | | OP7 | +30 | +35 | 3116 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | +30 | +35 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(4-CHLORBENZOYL)-PEROXID | ≤ 77 | | | | ≥ 23 | OP5 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | | | OP7 | | | 3106 | 20) |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | | ≥ 68 | | | | | Vyhrazeno | 29) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIKUMYLPEROXID | > 52 - 100 | | | | | OP8 | | | 3110 | 12) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | | | | Vyhrazeno | 29) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DICYKLOHEXYLPEROXYDIKARBONÁT | > 91 - 100 | | | | | OP3 | +10 | +15 | 3112 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 91 | | | | ≥ 9 | OP5 | +10 | +15 | 3114 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | +15 | +20 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIDEKANOYLPEROXID | ≤ 100 | | | | | OP6 | +30 | +35 | 3114 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,2-DI-(4,4-DI-(terc- | ≤ 42 | | | ≥ 58 | | OP7 | | | 3106 | |
| BUTYLPEROXY)-CYKLOHEXYL)-PROPAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 22 | | ≥ 78 | | | OP8 | | | 3107 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2,4-DICHLORBENZOYL)-PEROXID | ≤ 77 | | | | ≥ 23 | OP5 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | | | OP8 | +20 | +25 | 3118 | |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP7 | | | 3106 | |
| | pasta se | | | | | | | | | |
| | silikonovým | | | | | | | | | |
| | olejem | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-ETHOXYETHYL) | ≤ 52 | | ≥ 48 | | | OP7 | -10 | 0 | 3115 | |
| PEROXYDIKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1-(2-ETHYLHEXANOYLPEROXY)-1,3- | ≤ 52 | ≥ 45 | ≥ 10 | | | OP7 | -20 | -10 | 3115 | |
| DIMETHYLBUTYLPEROXYPIVALÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-ETHYLHEXYL) | > 77 - 100 | | | | | OP5 | -20 | -10 | 3113 | |
| PEROXYDIKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | ≥ 23 | | | OP7 | -15 | -5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 62 jako | | | | | OP8 | -15 | -5 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | -15 | -5 | 3120 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
| | (zmražené) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,2-DIHYDROPEROXYPROPAN | ≤ 27 | | | ≥ 73 | | OP5 | | | 3102 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(1-HYDROXYCYKLOHEXYL)PEROXID | ≤ 100 | | | | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIISOBUTYRYLPEROXID | > 32 - 52 | | ≥ 48 | | | OP5 | -20 | -10 | 3111 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 32 | | ≥ 68 | | | OP7 | -20 | -10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-ISOPROPYLBENZEN- | ≤ 82 | ≥ 5 | | | ≥ 5 | OP7 | | | 3106 | 24) |
| DIHYDROPEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIISOPROPYLPEROXYDIKARBONÁT | > 52 - 100 | | | | | OP2 | -15 | -5 | 3112 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | ≥ 48 | | | OP7 | -20 | -10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 28 | ≥ 72 | | | | OP7 | -15 | -5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DILAUROYLPEROXID | ≤ 100 | | | | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | | | 3109 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(3-METOXBUTYL)PEROXYKARBONÁT | ≤ 52 | | ≥ 48 | | | OP7 | -5 | +5 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-METHYLBENZOYL)PEROXID | ≤ 87 | | | | ≥ 13 | OP5 | +30 | +35 | 3112 | 3) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(3-METHYLBENZOYL)PEROXID+ | ≤ 20 + ≤ 18 | | ≥ 58 | | | OP7 | +35 | +40 | 3115 | |
| BENZOYL(3-METHYLBENZOYL) | + ≤ 4 | | | | | | | | | |
| PEROXID+DIBENZOYLPEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(4-METHYLBENZOYL)PEROXID | ≤ 52 jako | | | | | OP7 | | | 3106 | |
| | pasta se | | | | | | | | | |
| | silikonovým | | | | | | | | | |
| | olejem | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5-DI-(BENZOYL | > 82 - 100 | | | | | OP5 | | | 3102 | 3) |
| PEROXY)HEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 82 | | | ≥ 18 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 82 | | | | ≥ 18 | OP5 | | | 3104 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5-DI-(terc- | > 52 - 100 | | | | | OP7 | | | 3105 | |
| BUTYLPEROXY)HEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 47 | | | | | OP8 | | | 3108 | |
| | jako pasta | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | ≥ 48 | | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | | ≥ 23 | | OP8 | | | 3108 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5-DI-(terc- | > 86 - 100 | | | | | OP5 | | | 3101 | 3) |
| BUTYLPEROXY)HEX-3-IN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | > 52 - 86 | ≥ 14 | | | | OP5 | | | 3103 | 26) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5-DI- | ≤ 100 | | | | | OP5 | +20 | +25 | 3113 | |
| (2-ETHYLHEXANOYLPEROXY)HEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5- | ≤ 82 | | | | ≥ 18 | OP6 | | | 3104 | |
| DIHYDROPEROXYHEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 2,5-DIMETHYL-2,5-DI-(3,5,5- | ≤ 77 | ≥ 23 | | | | OP7 | | | 3105 | |
| TRIMETHYLHEXANOYLPEROXY)HEXAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1-DIMETHYL-3-HYDROXYBUTYL | ≤ 52 | ≥ 48 | | | | OP8 | 0 | +10 | 3117 | |
| PEROXYNEOHEPTANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIMYRISTYLPEROXYDIKARBONÁT | ≤ 100 | | | | | OP7 | +20 | +25 | 3116 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 42 jako | | | | | OP8 | +20 | +25 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-NEODEKANOYLPEROXY | ≤ 52 | ≥ 48 | | | | OP7 | -10 | 0 | 3115 | |
| ISOPROPYL)BENZEN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-n-NONANOYLPEROXID | ≤ 100 | | | | | OP7 | 0 | +10 | 3116 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-n-OKTANOYLPEROXID | ≤ 100 | | | | | OP5 | +10 | +15 | 3114 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(2-FENOXYETHYL)-PEROXY | > 85 - 100 | | | | | OP5 | | | 3102 | 3) |
| DIKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 85 | | | | ≥ 15 | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DIPROPIONYLPEROXID | ≤ 27 | | ≥ 73 | | | OP8 | +15 | +20 | 3117 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-n-PROPYLPEROXYKARBONÁT | ≤ 100 | | | | | OP3 | -25 | -15 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | | ≥ 23 | | | OP5 | -20 | -10 | 3113 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DISUKCINÁTPEROXID | > 72 - 100 | | | | | OP4 | | | 3102 | 3), 17) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | | | | ≥ 28 | OP7 | +10 | +15 | 3116 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| DI-(3,5,5-TRIMETHYLHEXANOYL) | > 38 - 82 | ≥ 18 | | | | OP7 | 0 | +10 | 3115 | |
| PEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | +10 | +15 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 38 | ≥ 62 | | | | OP8 | +20 | +25 | 3119 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ETHYL-3,3-DI-(terc-AMYLPEROXY) | ≤ 67 | ≥ 33 | | | | OP7 | | | 3105 | |
| BUTYRÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ETHYL-3,3-DI-(terc-BUTYLPEROXY) | > 77 - 100 | | | | | OP5 | | | 3103 | |
| BUTYRÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 77 | ≥ 23 | | | | OP7 | | | 3105 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | | | ≥ 48 | | OP7 | | | 3106 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-HEXYLPEROXYNEODEKANOÁT | ≤ 71 | ≥ 29 | | | | OP7 | 0 | +10 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| terc-HEXYLPEROXYPIVALÁT | ≤ 72 | | ≥ 28 | | | OP7 | +10 | +15 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 3-HYDROXY-1,1-DIMETHYLBUTYL | ≤ 77 | ≥ 23 | | | | OP7 | -5 | +5 | 3115 | |
| PEROXY-NEODEKANOAT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | -5 | +5 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 | ≥ 48 | | | | OP8 | -5 | +5 | 3117 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ISOPROPYL sec-BUTYL | ≤ 32 + ≤ 15 | ≥ 38 | | | | OP7 | -20 | -10 | 3115 | |
| PEROXYDIKARBONÁT+DI-sec- | - 18 | | | | | | | | | |
| BUTYLPEROXYDIKARBONÁT+DI- | ≤ 12 - 15 | | | | | | | | | |
| ISOPROPYLPEROXYDIKARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 + ≤ 28 | | | | | OP5 | -20 | -10 | 3111 | 3) |
| | + ≤ 22 | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ISOPROPYLKUMYL HYDROPEROXID | ≤ 72 | ≥ 28 | | | | OP8 | | | 3109 | 13) |
| | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| p-MENTHYL HYDROPEROXID | > 72 - 100 | | | | | OP7 | | | 3105 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 72 | ≥ 28 | | | | OP8 | | | 3109 | 27) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| METHYLCYKLOHEXANONPEROXID(Y) | ≤ 67 | | ≥ 33 | | | OP7 | +35 | +40 | 3115 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| METHYLETHYLKETONPEROXID(Y) | viz. | ≥ 48 | | | | OP5 | | | 3101 | 3), 8), |
| | poznámka 8) | | | | | | | | | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | viz. | ≥ 55 | | | | OP7 | | | 3105 | 9) |
| | poznámka 9) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | viz. | ≥ 60 | | | | OP8 | | | 3107 | 10) |
| | poznámka | | | | | | | | | |
| | 10) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| METHYLISOBUTYLKETONPEROXID(Y) | ≤ 62 | ≥ 19 | | | | OP7 | | | 3105 | 22) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | viz. | ≥ 70 | | | | OP8 | | | 3109 | 31) |
| | poznámka | | | | | | | | | |
| | 31) | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ORGANICKÝ PEROXID, KAPALNÝ, | | | | | | OP2 | | | 3103 | 11) |
| VZOREK | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ORGANICKÝ PEROXID, KAPALNÝ, | | | | | | OP2 | | | 3113 | 11) |
| VZOREK VYŽADUJÍCÍ ŘÍZENÍ | | | | | | | | | | |
| TEPLOTY | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ORGANICKÝ PEROXID, TUHÝ, | | | | | | OP2 | | | 3104 | 11) |
| VZOREK | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| ORGANICKÝ PEROXID, TUHÝ, | | | | | | OP2 | | | 3114 | 11) |
| VZOREK VYŽADUJÍCÍ ŘÍZENÍ | | | | | | | | | | |
| TEPLOTY | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 3,3,5,7,7-PENTAMETHYL- | ≤ 100 | | | | | OP8 | | | 3107 | |
| 1,2,4-TRIOXEPAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KYSELINA PEROXYOCTOVÁ, TYP D, | ≤ 43 | | | | | OP7 | | | 3105 | 13), 14), |
| STABILIZOVANÁ | | | | | | | | | | 19) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KYSELINA PEROXYOCTOVÁ, TYP E, | ≤ 43 | | | | | OP8 | | | 3107 | 13), 15), |
| STABILIZOVANÁ | | | | | | | | | | 19) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KYSELINA PEROXYOCTOVÁ, TYP F, | ≤ 43 | | | | | OP8 | | | 3109 | 13), 16), |
| STABILIZOVANÁ | | | | | | | | | | 19) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| KYSELINA PEROXYLAUROVÁ | ≤ 100 | | | | | OP8 | +35 | +40 | 3118 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| PINANYL HYDROPEROXID | > 56 - 100 | | | | | OP7 | | | 3105 | 13) |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 56 | ≥ 44 | | | | OP8 | | | 3109 | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| POLYETHER POLY-terc- | ≤ 52 | | ≥ 48 | | | OP8 | | | 3107 | |
| BUTYLPEROXY-KARBONÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1,3,3- | ≤ 100 | | | | | OP7 | | | 3105 | |
| TETRAMETHYLBUTYL HYDROPEROXID | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1,3,3-TETRAMETHYLBUTYL | ≤ 100 | | | | | OP7 | +15 | +20 | 3115 | |
| PEROXY-2ETHYLHEXANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1,3,3-TETRAMETHYLBUTYL | ≤ 72 | | ≥ 28 | | | OP7 | -5 | +5 | 3115 | |
| PEROXYNEODEKANOÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| " | ≤ 52 jako | | | | | OP8 | -5 | +5 | 3119 | |
| | stabilní | | | | | | | | | |
| | disperze | | | | | | | | | |
| | ve vodě | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 1,1,3,3-TETRAMETHYLBUTYL | ≤ 77 | ≥ 23 | | | | OP7 | 0 | +10 | 3115 | |
| PEROXYPIVALÁT | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
| 3,6,9-TRIETHYL-3,6,9-TRIMETHYL- | ≤ 42 | ≥ 58 | | | | OP7 | | | 3105 | 28) |
| 1,4,7-TRIPEROXONAN | | | | | | | | | | |
+---------------------------------+-------------+---------+---------+---------+------+--------+---------+----------+-----------+------------+
Poznámky k pododdílu 2.2.52.4:
1) Ředidlo typu B může být vždy nahrazeno ředidlem typu A. Bod varu ředidla typu B musí být nejméně o 60 °C vyšší než je SADT organického peroxidu.
2) Obsah aktivního kyslíku ≤ 4,7 %.
3) Vyžaduje se bezpečnostní značka pro vedlejší nebezpečí "VÝBUŠNÝ" podle vzoru 1 (viz 5.2.2.2.2).
4) Ředidlo může být nahrazeno di-terc-butylperoxidem.
5) Obsah aktivního kyslíku ≤ 9 %.
6) Nejvýše 9 % peroxidu vodíku; obsah aktivního kyslíku ≤ 10 %.
7) Smí se použít pouze nekovových obalů.
8) Obsah aktivního kyslíku > 10 % a ≤ 10,7 %, s vodou nebo bez vody.
9) Obsah aktivního kyslíku ≤ 10 %, s vodou nebo bez vody.
10) Obsah aktivního kyslíku ≤ 8,2 %, s vodou nebo bez vody.
11) Viz 2.2.52.1.9.
12) Do 2 000 kg na nádobu přiřazenou ORGANICKÉMU PEROXIDU TYPU F, na základě výsledků zkoušek ve velkém měřítku.
13) Vyžaduje se bezpečnostní značka pro vedlejší nebezpečí "ŽÍRAVÝ" podle vzoru č. 8 (viz 5.2.2.2.2).
14) Přípravky kyseliny peroxyoctové, které odpovídají kritériím Příručky zkoušek a kritérií, odstavce 20.4.3d).
15) Přípravky kyseliny peroxyoctové, které odpovídají kritériím Příručky zkoušek a kritérií odstavce 20.4.3e).
16) Přípravky kyseliny peroxyoctové, které odpovídají kritériím Příručky zkoušek a kritérií, odstavce 20.4.3f).
17) Přidáním vody k tomuto organickému peroxidu se zmenší jeho tepelná stabilita.
18) Pro koncentrace pod 80 % se nevyžaduje bezpečnostní značka pro vedlejší nebezpečí "ŽÍRAVÝ" podle vzoru č. 8 (viz 5.2.2.2.2).
19) Směsi s peroxidem vodíku, vodou a kyselinou(ami).
20) S ředidlem typu A, s vodou nebo bez vody.
21) S nejméně 25 % hm. ředidla typu A a k tomu ethylbenzen.
22) S nejméně 19 % hm. ředidla typu A a k tomu methylisobutylketon.
23) S méně než 6 % di-terc-butylperoxidu.
24) Do 8 % 1-isopropylhydroperoxy-4-isopropylhydroxybenzénu.
25) Ředidlo typu B s bodem varu vyšším než 110 °C.
26) Obsah hydroperoxidů < 0,5 %.
27) Pro koncentrace nad 56 % se vyžaduje bezpečnostní značka pro vedlejší nebezpečí "ŽÍRAVÝ" podle vzoru č. 8 (viz 5.2.2.2.2).
28) Obsah aktivního kyslíku ≤ 7,6 % v ředidle typu A s bodem varu v rozmezí 200 °C až 260 °C.
29) Nepodléhá ustanovením ADR pro třídu 5.2.
30) Ředidlo typu B s bodem varu >130 °C.
31) Aktivní kyslík <6,7 %.